Coordination pillared-layer type compounds having pore surface functionalization by anionic sulfonate groups.

نویسندگان

  • Satoshi Horike
  • Sareeya Bureekaew
  • Susumu Kitagawa
چکیده

Pillared-layer type 3D porous coordination polymers with 2-sulfonylterephthalate, 4,4'-bipyridine and Zn(2+) have metal-free sulfonate groups on the pore walls, providing Lewis basic property for acid guest sorption.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Influence of anionic sulfonate-containing and nitrogen-containing mixed-ligands on the structures of silver coordination polymers.

In this article, a series of mixed-ligand Ag(i) coordination polymers, namely, Ag(L1)H(2)O (), Ag(2)(hmt)(2)(L1)(2) (), [Ag(HL2)]H(2)O (), [Ag(L2)(biim)][Ag(biim)] (), [K(5)(L3)(2)][Ag(H(2)O)(2)] (), [Ag(2)(L3)(3-iso)][Ag(3-iso)]5H(2)O (), [Ag(3)(L3)(bipy)(3)(H(2)O)]6H(2)O (), [Ag(3)(L3)(biim)(3)]H(2)O (), and [Ag(3)(L3)(hmt)(2)(H(2)O)(3)]H(2)O () (where hmt = hexamethylenetetramine, bipy = 4,4...

متن کامل

Systematic investigation on the coordination chemistry of a sulfonated monoazo dye: ligand-dominated d- and f-block derivatives.

Ten coordination compounds based on a sulfonated monoazo dye, formulated as M(H(2)O)(2)(4,4'-abs)(2) (M = Mn , Co , Cu , Zn , Cd and Pb ; 4,4'-abs = 4-aminoazobenzene-4'-sulfonic anion), Ag(4,4'-abs) (), [Ln(H(2)O)(phen)(2)(4,4'-abs)(3)].3H(2)O (Ln = Gd , Tb , and Ho ; phen = 1,10-phenanthroline), as well as the parent ligand L [(4,4'-Habs)(2).4H(2)O] and precursor NaL.HL [Na(4,4'-abs)(4,4'-Hab...

متن کامل

A Series of Guest-Defined Metal-Complex/Disulfonate Frameworks of Hydrogen-Bonded [Co(en)2(ox)] and 2,6-Naphtalenedisulfonate

A new series of soft-host frameworks assembled by charge-assisted hydrogen bonds between a cationic metal complex (MC) and an anionic disulfonate specifically [Co(en)2(ox)] and 2,6-naphthalenedisulfonate (NDS), is synthesized and structurally characterized. The five new compounds have a general formula (MC)2(NDS) ·n(guest) where guests are H2O, dimethylformamide (DMF), dimethyl sulfoxide (DMSO)...

متن کامل

Hydrogen-bonded metal-complex sulfonate (MCS) inclusion compounds: effect of the guest molecule on the host framework.

Soft molecular host frameworks made of the hydrogen-bonded metal complex (MC) Co(NH3)(6)3+ and 4,4'-biphenyldisulfonate (BPDS) include different guest molecules to form inclusion compounds of the type (MC)2(BPDS)3.n(guest). Structurally characterized were six compounds with guest molecules of DMSO, DMF, piperidine, acetone, acetonitrile, and THF. The metal-complex sulfonate frameworks in all of...

متن کامل

Hydrogen-bonded inclusion compounds with reversed polarity: anionic metal-complexes and cationic organic linkers.

Synthesized and structurally characterized is a new series of soft-host frameworks assembled by charge-assisted hydrogen bonds between an anionic metal complex (MC) and cationic organic linkers (OL), specifically [Co(en)(ox)(2)](-) and diprotonated 4,4'-bipyridinium (H(2)bpy) or 1,2-bis(4-pyridinium)ethylene (H(2)bpye). While frameworks built of cationic complexes and anionic organic linkers ar...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 4  شماره 

صفحات  -

تاریخ انتشار 2008